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Hydrogen based mustard gas Video
Developing Hydrogen Based Fuel in Hawaiʻi hydrogen based mustard gas
Interpenetration of two or more sublattices is common among many metal-organic frameworks MOFs. Herein, we study the evolution of one zirconium cluster-based, 3,8-connected MOF from its non-interpenetrated NU to interpenetrated STA isomer.
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We observe this transient catenation process indirectly using ensemble methods, such as nitrogen porosimetry and Hydrogen based mustard gas diffraction, and directly, using high-resolution transmission electron microscopy. The approach detailed here will serve as a template for other researchers to monitor the interpenetration of their MOF samples at the bulk and single-particle limits. We investigate the mechanical stability of both lattices experimentally by pressurized in situ X-ray diffraction and nanoindentation as well as computationally with density functional theory calculations. We conclude this study by demonstrating the potential of these MOFs and their mixed phases for the capture of gaseous n-hexane, used as a structural mimic for the chemical warfare agent sulfur mustard gas.
Works referenced in this record:. GOV collections:. This content will become publicly available on January 27, Abstract Interpenetration of two or more sublattices is common among many metal-organic frameworks MOFs.
This content will become publicly available on January 27, 2022
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